Propergol Aging

Experimental demonstration of polymer matrix oxidation and validation of the oxidation model

 

Thermo-oxidation of binder (DMPE)

Demonstration of surface oxidation after 6-month ageing at 40ºC and 60º C but not at room temperature (homogeneous oxidation) using two different techniques.

 

Oxygen concentration profile using MEB/EDX (DMAS)

 

Oxygen concentration profile by elemental chemical analysis

External oxidation layer < 3 mm (approx. 10% of height)

 

Ageing at 60 °C

Conclusions

  • Conformity of simulated profiles with SEM data
  • Diffusion limited by oxidized surface layer
  • Faster saturation at 60°C due to accelerated oxidation
     

[Theme] Energetic materials, emissions and atmospheric dispersion